· The mechanisms of pyrite formation are reviewed. Advances since 1994 in our understanding of the mechanisms and rate of pyrite formation, the role of bacteria in the formation of pyrite, framboid formation, and incorporation of impurities into pyrite are emphasized.
· ELSEVIER Marine Chemistry 57(1997) 187-193 Pyrite formation under conditions approximating those in anoxic sediments: II. Influence of precursor iron minerals and organic matter John W. Morse *, Qiwei Wang Department of Oceanography, Texas A & M ...
· Sedimentary pyrite formation during early diagenesis is a major process for controlling the oxygen level of the atmosphere and the sulfate concentration in seawater over geologic time. The amount of pyrite that may form in a sediment is limited by the rates of supply of decomposable organic matter, dissolved sulfate, and reactive detrital iron ...
Dynamics of pyrite formation and organic matter sulfurization in organic-rich carbonate sediments Lubna Shawara, Itay Halevyb, Ward Said-Ahmada, Shimon Feinsteinc Valeria Boykoc, Alexey Kamyshnyc, Alon Amrania, aInstitute of Earth Sciences, Hebrew University, Jerusalem, Israel ...
· About 15% of the pyrite in sediments of the euxinic basin of Green Lake forms in the water column. The bulk of pyrite in both euxinic and oxic sediments forms in the upper ∼10 cm of the sediment and is limited by availability of reactive iron.
Qiwei Wang, John W. Morse, Pyrite formation under conditions approximating those in anoxic sediments I. Pathway and morphology, Marine Chemistry, 10.1016/0304-4203(95)00082-8, 52, 2, (99-121), (1996). Crossref Volume 17, Issue 4 October 1994 Pages ...
Pyrite formation under conditions approximating those in anoxic sediments: II. Influence of precursor iron minerals and organic matter Author links open overlay panel John W. Morse Qiwei Wang
Abstract Pyrite (FeS 2) forms commonly in salt marsh sediments and acts as a crucial control on the amount of sulfur in its various forms (SO 4 2-, H2 S, etc.) that remains in the environment. A better understanding of the mechanisms behind pyrite formation is
· O., Gordeev, V. (2018) Framboidal pyrite formation in the bottom sediments of the South Caspian Basin under conditions of hydrogen sulfide contamination. Russian Journal of Earth Sciences 18, 1–10.). Poorly understood issues regarding the rapid ...
About 15% of the pyrite in sediments of the euxinic basin of Green Lake forms in the water column. The bulk of pyrite in both euxinic and oxic sediments forms in the upper ∼10 cm of the sediment and is limited by availability of reactive iron.
Sedimentary pyrite formation during early diagenesis is a major process for controlling the oxygen level of the atmosphere and the sulfate concentration in seawater over geologic time. The amount of pyrite that may form in a sediment is limited by the rates of supply of decomposable organic matter, dissolved sulfate, and reactive detrital iron minerals. Organic matter appears to be the major ...
· Based on pyrite textures, S-isotopic compositions of water-column and sediment sulfides, and settling rate calculations, about 70% of the pyrite burial flux to the Pettaquamscutt sediments is accounted for by framboids forming at the oxic-anoxic interface and
Pyrite synthesis was examined in the laboratory, and the chemical, crystallographic and textural results were compared with naturally occurring pyrite in marine sediment. The path of pyrite formation begins with reaction of hydrogen sulfide and dissolved iron. The first product is either amorphous iron sulfide or mackinawite with composition FeS ...
· The formation of pyrite crystals depends mainly on the iron content of the sediment. The process of pyrite formation in sediments results from the action of bacteria, which reduce sulphate ions (dissolved in the pore water) to sulphide. If there is iron present, iron ...
· The initial reaction products are iron monosulfide minerals that may subsequently transform to pyrite by reaction with polysulfides or other reactive oxidants (e.g., Morse et al., 1987). Pyrite formation in sediments is thought to be limited either by the microbial
Sedimentary pyrite formation: An update - ScienceDirect
· With an annual formation of at least 5 million tons, pyrite (FeS 2) is the thermodynamically stable end product of iron compounds reacting with sulfide in reduced sediments, with the latter being produced mainly by microbial sulfate reduction. Consequently, pyrite is the most abundant iron−sulfur mineral on Earth''s surface (1).
Boesen C. and Postma D. (1988) Pyrite formation in the anoxic sediments of the Baltic. Am. J Sci. 288, 575-603. Google Scholar Calvert S. E. and Karlin R. E. (1991) Relationships between sulfur, organic carbon and iron in the modern sediments of 55
Pyrite and siderite formation in brackish and freshwater swamp sediments. / Postma, Diederik Jan. In: American Journal of Science, Vol. 282, 1982, p. 1151-1183. Research output: Contribution to journal › Journal article › Research › peer-review
Anatomy, Evolution, and Paleoenvironmental Interpretation of an Ancient Arctic Coastal Plain: Integrated Paleopedology and Palynology from the Upper Cretaceous (Maastrichtian) Prince Creek formation, North Slope, Alaska, USA
· If pyrite formation in the sediments is indeed inhibited, it is likely associated with the availability of dissolved FeS rather than H 2 S. At pH > 7, FeS m hydrolysis is negligible and dissolved FeS is controlled by the intrinsic solubility of solid-phase FeS FeS (aq) /FeS (s) = 10 −6 ( Rickard, 2006 ).
that the bacteria that live and thrive in the reducing sediments that favor pyrite formation may also be preserved in areas of pyrite precipitation. With pyrite being a ubiquitous early diagenetic mineral in all types of sedimentary rocks, there is an obvious potential
Postma D 1982 Pyrite and Siderite Formation in Brackish and Fresh Water Swamp Sediments;Amer. J. Sci. 282 1151–1183. Article Google Scholar Raiswell R 1982 Pyrite Texture, Isotropic Composition and the Availability of Iron;Amer. J. Sci. 282
· Formation of the FeS precursor depends on the availability of Fe(II), and so, the location of pyrite formation and the ultimate amount formed, depend on where in the sediment Fe becomes available for FeS precipitation. Fe(II) in sediment porewater may come from
modes of formation for pyrite spheres: infill of gas bubbles within the sediment, and infill ofTasmanites cysts. ... texturally comparable pyrite spheres occur in sediments of various ages. Also, candidates for modern analogs have been described from recent sed ...
We demonstrate that Fe isotope fractionation accompanies abiotic pyrite formation in the absence of Fe(II) redox change. Combined fractionation factors between Fe(II)(aq), mackinawite, and pyrite permit the generation of pyrite with Fe isotope signatures that nearly encapsulate the full range of sedimentary δ(56)Fe(pyrite) recorded in Archean to modern sediments.
A new method was used to study the formation of pyrite plus elemental sulfur during 3 5 SO 4 2‒ reduction experiments in salt marsh sediments: the reduction with chromium(II) of pyrite and elemental sulfur to hydrogen sulfide. It is both more specific and more ...
· These sediments contain a small lithogenous fraction and a large biogenous, organic C-rich fraction, which decays by sulfate reduction in an iron-rich water column to form pyrite-rich sediment. Other anaerobic/euxinic samples from the Black Sea, Orca Basin, and Kau Bay contain lower concentrations of biogenous sediment and are not therefore ...
Raiswell, R. and Canfield, D.E. (1998) Sources of iron for pyrite formation in marine sediments. American Journal of Science, 298 (3). pp. 219-245. ISSN 0002-9599 Abstract More than two hundred aerobic continental margin, aerobic deep sea, dysaerobic, and ...
Pyrite''s metallic luster and pale brass-yellow hue give it a superficial resemblance to gold, hence the well-known nickname of fool''s gold.The color has also led to the nicknames brass, brazzle, and Brazil, primarily used to refer to pyrite found in coal. The name pyrite is derived from the Greek πυρίτης λίθος (pyritēs lithos), "stone or mineral which strikes fire", in turn from ...
whether it be in the sediments (Cutter and Velinsky, 1988) or in the water column (Muramoto et al., 1991 ). Apparently greigite formation and framboid formation are linked to the oxic-anoxic transition. The discovery of pyrite framboids suspended
Although pyrite was only detected in the sediments and not in the water column, sulfate-rich enrichment cultures from this lake led to rapid pyrite formation after 21 days of culture (Berg et al., 2020).